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排序方式: 共有6266条查询结果,搜索用时 31 毫秒
81.
Yuemin Lin Yuanyuan Zhang Renfeng Nie Kai Zhou Yao Ma Mingjie Liu Dan Lu Zongbi Bao Qiwei Yang Yiwen Yang Qilong Ren Zhiguo Zhang 《Frontiers of Chemical Science and Engineering》2022,16(12):1782
Ultra-dispersed Ni nanoparticles (7.5 nm) on nitrogen-doped carbon nanoneedles (Ni@NCNs) were prepared by simple pyrolysis of Ni-based metal–organic-framework for selective hydrogenation of halogenated nitrobenzenes to corresponding anilines. Two different crystallization methods (stirring and static) were compared and the optimal pyrolysis temperature was explored. Ni@NCNs were systematically characterized by wide analytical techniques. In the hydrogenation of p-chloronitrobenzene, Ni@NCNs-600 (pyrolyzed at 600 °C) exhibited extraordinarily high performance with 77.9 h–1 catalytic productivity and > 99% p-chloroaniline selectivity at full p-chloronitrobenzene conversion under mild conditions (90 °C, 1.5 MPa H2), showing obvious superiority compared with reported Ni-based catalysts. Notably, the reaction smoothly proceeded at room temperature with full conversion and > 99% selectivity. Moreover, Ni@NCNs-600 afforded good tolerance to various nitroarenes substituted by sensitive groups (halogen, nitrile, keto, carboxylic, etc.), and could be easily recycled by magnetic separation and reused for 5 times without deactivation. The adsorption tests showed that the preferential adsorption of –NO2 on the catalyst can restrain the dehalogenation of p-chloronitrobenzene, thus achieving high p-chloroaniline selectivity. While the high activity can be attributed to high Ni dispersion, special morphology, and rich pore structure of the catalyst. 相似文献
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83.
Yuxuan Xu Guanglong Dai Shibin Nie Jinian Yang Song Liu Hong Zhang Xiang Dong 《Frontiers of Chemical Science and Engineering》2022,16(10):1493
Metal−organic framework-derived materials have attracted significant attention in the applications of functional materials. In this work, the rod-like nickel-based metal−organic frameworks were first synthesized and subsequently employed as the hard templates and nickel sources to prepare the whisker-shaped nickel phyllosilicate using a facile hydrothermal technology. Then, the nickel phyllosilicate whiskers were evaluated to enhance the mechanical, thermal, flammable, and tribological properties of epoxy resin. The results show that adequate nickel phyllosilicate whiskers can disperse well in the matrix, improving the tensile strength and elastic modulus by 13.6% and 56.4%, respectively. Although the addition of nickel phyllosilicate whiskers could not obtain any UL-94 ratings, it enhanced the difficulty in burning the resulted epoxy resin nanocomposites and considerably enhanced thermal stabilities. Additionally, it was demonstrated that such nickel phyllosilicate whiskers preferred to improve the wear resistance instead of the antifriction feature. Moreover, the wear rate of epoxy resin nanocomposites was reduced significantly by 80% for pure epoxy resin by adding 1 phr whiskers. The as-prepared nickel phyllosilicate whiskers proved to be promising reinforcements in preparing of high-performance epoxy resin nanocomposites. 相似文献
84.
混凝土拖泵S管部件由于结构特殊,且具有一定尺寸精度及形位公差要求,因而装夹、校正、加工非常困难,介绍一种在镗床上加工此类工件的工艺方法,并对夹具和刀具进行了介绍。 相似文献
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86.
针对现有的电力系统次同步振荡的检测方法存在对噪声敏感、振荡的特征和变化趋势难以获得的局限性,提出将频率切片小波变换(FSWT)方法应用于次同步振荡的分析和参数辨识。FSWT方法自由切割时频面,实现信号频率区间的灵活分割,可以实现对次同步振荡信号的总体和细化分析。首先,采用FSWT方法对含噪的次同步振荡信号进行总体时频分析,得到其时频能量分布。根据时频能量分布,可以预判是否发生次同步振荡、确定模态分量的数量及其频率分布区间。然后,合理选择频率切片区间,进行细化特征分析,通过对信号特征频率切片区间信号的重构,实现了次同步振荡的模态分量的分离及提取。最后,结合Hilbert变换获得高准确度的次同步振荡模态参数。 相似文献
87.
通过高压扭转实验,在350℃条件下将难熔金属纯钼粉末制备成相对密度达0.98以上的金属钼坯,利用多种检测手段分析了高压扭转过程中钼粉颗粒孔隙演变及致密强化规律。通过改变预压钼坯压力参数,探讨了压力对压扭钼坯微观结构和力学性能及其热稳定性的影响。结果表明:压力由2.0GPa增大到3.0GPa,压扭钼坯致密度提升显著,其内部亚晶尺寸细化,微观应变增加,试样整体显微硬度值随压力增大而升高,边缘处略有降低。随压力增大,DSC后组织未发生显著长大,热稳定性较好。 相似文献
88.
研究了提Al降Nb对GH706合金经过高温长时时效处理前后的组织与力学性能的影响。结果表明,提Al降Nb的成分改进抑制了高温不稳定存在的γ′′相、η相及Laves相和δ相等TCP相的析出,同时,在经过750℃保温500h的处理后,只存在γ′和η相的轻微长大,力学性能下降幅度有限,仍保持在一个较高的水平,而未进行成分改进的合金(传统GH706)中的析出相等均发生明显长大,力学性能下降幅度较大,可见提Al降Nb的成分改进可使得合金在更高的温度服役。 相似文献
89.
Particle reinforced magnesium matrix composite(PMMC) possesses the merits of high specific strength, high specific modulus, better dimensional stability, good wear resistance and lower production cost, which is thought as a promising material in the field of aerospace, automobile, electronic communication, etc. To eliminate the casting defect, the PMMC is usually experienced hot deformation process. The present paper mainly focuses on the deformation behavior of PMMCs. First, the development of PMMCs based on particle size is introduced. Then, the hot deformation technology and deformation mechanism of PMMCs at elevated temperature are given and analyzed, respectively. After reviewing the dynamic recrystallization and texture of PMMCs, its future development is suggested based on the current research progress. 相似文献
90.